Exam 2 aromatics rxn Study guides, Class notes & Summaries

best to prepare m-choroaniline from benzene? HNO2/H2SO4; Cl2/AlCl3; SN/HCl; HO- best to prepare p-chlorotoluene in high yield? start with p-aminotoluene; NaNO2/HCl, 0C; CuCl best to prepare m-dibromobenzene from benzene? nitrate; brominate; Sn/HCl; NaNO2; 0 C; CuBr electrophilic aromatic substitution Nitro ? N Group, Nitrogen M-director, destabilized META, less than ortho, para electrophilic aromatic substitution -NHCOCH3 ? Activator, o-p director reaction with Bromine substituent ? Br...

CHEM 286 Theory Exam Covered Topics: SPECTROSCOPY Labeling IR spectrum: • Draw cmpd structure on spectrum, ID all fxnal groups present, assign important bands in spectrum (str + bends) • If s everal bands exist for same fxnal group, use bracket to specifically cover correct set of signals • MEMORIZE Vibration type Functional Group Wavelength Characteristic OH stretch Alcohol/Phenol 3200-3600 Broad/strong Acid (-COOH centered ~3000) 2500-3200 Broad/strong NH stretch 3200-3500 Broad/strong C...